One of the more entertaining villains on our list, Hans Landa (aka "The Jew Hunter") of 'Inglourious Basterds' knows how to put on a show. His every move is very calculated and precise, but he's also a little flamboyant and charming, no? It's that very charm that puts the subjects of his interrogations at such unease -- you can never be sure if he's being sincere or if he's going to have you killed quicker than he can snap his fingers. But he also gave us one of the most delightfully memorable bad guy lines ever: "That's a bingo!"