This past week's all-new 'Supernatural' installment, "Devil May Care," got the boys back in business following the season 9 premiere, but things truly start to get out of hand in next week's "I'm No Angel." Everyone's favorite outcast Castiel returns, hunted by heavenly and demonic forces alike, so what do we learn from the first photos of the latest episode?

While it looks as if Castiel will have even more trouble adapting to his newfound humanity than we might have thought, the new looks of next Tuesday's "I'm No Angel" also showoff the episode's mysterious new villain, April, played by Shannon Lucio of the Marvel's 'Agents of S.H.I.E.L.D.' pilot. Here's what The CW had to say of the latest 'Supernatural' installment:

CASTIEL IS HUNTED BY THE ANGELS --- Ezekiel tells Dean (Jensen Ackles) a group of angels is hunting Castiel (Misha Collins). Dean and Sam (Jared Padalecki) race to find their friend before the angels do. Meanwhile, a homeless Castiel is trying to make his way through the city and comes across some unexpected surprises.

You can check out the latest photos from next week's 'Supernatural' below, and stay tuned for the latest from Felicia Day's return as Charlie Bradbury in the 'Wizard of Oz'-themed "Slumber Party." Tell us what you want to see from the new season of 'Supernatural' in the comments!